The step 2 interval 25/21 is 302 cents, an acceptable minor third to western ears, but equal temperament changes it to a flat-sounding 292 cents.
The step 12 interval 25/9 (B note) is totally outside of the western 12-tone system.
This chart shows the intersection between the Bohlen Pierce scale and the 7-limit just intonation system. The D and B notes (in blue) suffer the problems mentioned above. The difference between cents and round hundreds is a rough indicator of how alien the interval will sound compared to traditional western harmony.
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